Class 12 > PYQ CHEMISTRY > 2017 > Set 3

2017

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Q11
Give reasons :
(i) Acetylation of aniline reduces its activation effect.
(ii) CH₃NH₂ is more basic than C₆H₅NH₂.
(iii) Although –NH₂ is o/p directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

Q12
Give reasons:
(i) Thermal stability decreases from H₂O to H₂Te.
(ii) Fluoride ion has higher hydration enthalpy than chloride ion.
(iii) Nitrogen does not form pentahalide.

Q13
Define the following :
(i) Anionic detergents
(ii) Limited spectrum antibiotics
(iii) Tranquilizers

Q14
Write the structures of the monomers used for getting the following polymers :
(i) Nylon-6
(ii) Melamine – formaldehyde polymer
(iii) Teflon

Q16
(a) Write the principle of method used for the refining of germanium.
(b) Out of PbS and PbCO₃ (ores of lead), which one is concentrated by froth floatation process preferably?
(c) What is the significance of leaching in the extraction of aluminium ?

Q17
Following compounds are given to you:
2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane
(i) Write the compound which is most reactive towards SN2 reaction.
(ii) Write the compound which is optically active.
(iii) Write the compound which is most reactive towards β-elimination reaction.

Q19
Write one difference between each of the following :
(i) Multimolecular colloid and Macromolecular colloid
(ii) Sol and Gel
(iii) O/W emulsion and W/O emulsion

Q20
(i) What type of isomerism is shown by the complex [Co(en)₃]Cl₃?
(ii) Write the hybridisation and magnetic character of [Co(C₂O₄)₃]³⁻ (At. no. of Co = 27)
(iii) Write IUP AC name of the following Complex [Cr(NH₃)₃Cl₃].

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